Bis(2-amino-4-methylpyridinium) bis(pyridine-2,6-dicarboxylato)cuprate(II)
نویسندگان
چکیده
The asymmetric unit of the title compound, (C(6)H(9)N(2))(2)[Cu(C(7)H(3)NO(4))(2)], contains half of a [Cu(pydc)(2)](2-) (pydcH(2) is pyridine-2,6-dicarb-oxy-lic acid) anion and one protonated 2-amino-4-methyl-pyridine (2a4mpH)(+) counter-ion. The anion is a six-coordinated complex with a distorted CuN(2)O(4) octa-hedral geometry around the Cu(II) ion. N-H⋯O and C-H⋯O hydrogen bonds along with π-π contacts between the pyridine rings of the (2a4mpH)(+) cations [centroid-centroid distance = 3.573 (2) Å] stabilize the crystal structure.
منابع مشابه
Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)cuprate(II) trihydrate
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011